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991.
Wally L. Chang Kurt C. Frisch Kaneyoshi Ashida 《Journal of polymer science. Part A, Polymer chemistry》1989,27(11):3637-3649
The anionic polymerization of ?-caprolactam (CLM) has been shown to proceed at high reaction rate when catalyzed by metallic lactamates and initiated by acyllactams. The role of initiator and catalyst concentration on the process of ?-caprolactam anionic polymerization has been explored, with the aim of selecting the most suitable experimental conditions for reaction injection molding (RIM). The overall polymerization rates and physical properties for reaction injection molding of star-shaped nylon 6 homopolymer have been studied by the quasi-adiabatic process. In order to model the actual rapid molding conditions, time vs. temperature reaction profiles were measured, and the relative rates of polymerization subsequently determined from these data. 相似文献
992.
Monica L. Smith 《Complexity》2007,12(4):28-35
When depicted on maps as homogenous territorial wholes, ancient states are visually summarized as static entities in a way that conceals the highly fluid dynamics of polity formation, maintenance, and growth. Models derived from studies of animal behavior show that “territory” does not consist of an undifferentiated use of the landscape. Instead, the concept of territory can be parsed into a series of resource‐rich nodes linked by corridors of access, surrounded by unutilized regions and boundaries marked at points of competition. Ancient human groups also can be analyzed as having perceived and occupied landscapes through strategies of flexible networks in which nodes and corridors were surrounded by unutilized spaces around which boundaries were selectively identified and defended. This strategy is identifiable in human social groups at different levels of complexity ranging from hunter‐gatherers through ancient chiefdoms and states. © 2007 Wiley Periodicals, Inc. Complexity 12: 28–35, 2007 相似文献
993.
994.
G. L. Litvinov 《Journal of Mathematical Sciences》1987,38(2):1734-1761
995.
A fully coupled formulation combining reactive transport and an existing thermo-hydro-mechanical (THM) code is presented.
Special attention has been given to phenomena likely to be encountered in clay barriers used as part of containment systems
of nuclear waste. The types of processes considered include hydrolysis, complex formation, oxidation/reduction reactions,
acid/base reactions, precipitation/dissolution of minerals and cation exchange. Both kinetically-controlled and equilibrium-controlled
reactions have been incorporated. The total analytical concentrations (including precipitated minerals) are adopted as basic
transport variables and chemical equilibrium is achieved by minimizing Gibbs Free Energy. The formulation has been incorporated
in a general purpose computer code capable of performing numerical analysis of engineering problems. A validation exercise
concerning a laboratory experiment involving the heating and hydration of an expansive compacted clay is described. 相似文献
996.
Frozen Landweber Iteration for Nonlinear Ill-Posed Problems 总被引:1,自引:0,他引:1
J. Xu B. Han L. Li 《应用数学学报(英文版)》2007,23(2):329-336
In this paper we propose a modification of the Landweber iteration termed frozen Landweberiteration for nonlinear ill-posed problems.A convergence analysis for this iteration is presented.The numericalperformance of this frozen Landweber iteration for a nonlinear Hammerstein integral equation is compared withthat of the Landweber iteration.We obtain a shorter running time of the frozen Landweber iteration based onthe same convergence accuracy. 相似文献
997.
998.
The behaviour of the amplitude-frequency characteristics of families of periodic solutions, produced from the equilibrium position of a system, is established by a qualitative investigation of the equation of the oscillations of a pendulum, the length of which is an arbitrary periodic function of time. The non-local conditions for their stability and instability, expressed in terms of the amplitude and frequency of the oscillations, are obtained. The results are used when discussing the parametric and self-excited oscillatory model of a swing. In the parametric model the length of a swing is a specified periodic function of time, and in the self-excited oscillatory model it is a function of the phase coordinates of the system. For an appropriate choice of these functions, both systems have a common periodic solution. It is shown that the parametric model leads to an erroneous conclusion regarding the instability of the periodic mode, which is in fact realized in the oscillations of a swing, whereas the self-excited oscillatory model indicates its stability. 相似文献
999.
A. S. Boreysho S. L. Druzhinin V. M. Malkov I. A. Kiselev A. V. Morozov A. E. Orlov A. V. Savin I. V. Shatalov V. I. Zapryagaev A. V. Sobolev 《Thermophysics and Aeromechanics》2007,14(4):561-576
The matter of development of a high-performance pressure recovery system (PRS) for a high-power HF/DF laser is discussed.
A sequence of design steps is proposed, which involves estimation of basic characteristics of PRS components with the help
of one-dimensional integral and semi-empirical procedures; simulation, to be performed using three-dimensional non-stationary
Navier — Stokes equations; experimental modelling aimed at verification of the calculation procedures and at refinement of
obtained parameters; and a fullscale experiment. An ejector-type system providing for recovery of pressure from 12 Torr to
atmospheric pressure in the gas-dynamic system of an HF/DF laser of several-tens-kilowatt power is developed. Matching conditions
for parameters of individual PRS components as well as joint functioning of the PRS with a continuous chemical laser in an
integral complex are analysed. Conditions for minimization of mass-dimensional characteristics of the laser-PRS complex necessary
for the development of ground-based mobile systems are identified. 相似文献
1000.
K.T.A.L. Burm 《等离子体物理论文集》2007,47(6):458-464
The discharge behaviour of an atmospheric dielectric barrier parallel plate discharge, used for surface treatment, is studied. Since an uniform plasma is preferable for surface treatment, filaments must be avoided in the discharge. The occurrence of filaments can be detected by measuring the current flowing through the discharge. Current and voltage measurements give an indication of the power consumption by the plasma. The power consumption of the plasma as function of the applied frequency is examined. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献